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The kinetics of the bimolecular self-reaction of t-butyl radicals in solution. II. Disproportionation/combination ratios

✍ Scribed by Hans-Herbert Schuh; Hanns Fischer

Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
952 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Disproportionation/combination ratios P~d~/P~c~ of self‐reacting t‐butyl radicals are determined as a function of solvent and temperature. the observed large solvent and temperature dependences are ascribed to anisotropic reorientational motions of the radicals during their encounter in the solvent cage. Results for other alkyl radicals are compatible with this concept.

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