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Reaction of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2with internal alkynes: Synthesis and structural characterization of ruthenium-cyclobutadiene and ruthenacyclopentatriene complexes

✍ Scribed by ZaoZao Qiu; Yi Sun; ZuoWei Xie


Book ID
107349243
Publisher
SP Science China Press
Year
2010
Tongue
English
Weight
605 KB
Volume
53
Category
Article
ISSN
1674-7291

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Cyclopentadienyl and its derivatives (Cp ligands) are among the most extensively utilized p ligands in organometallic chemistry. In most organometallic reactions of transitionmetal complexes, the h 5 -Cp ligand plays the role of a spectator that stays tightly bound in h 5 fashion to the metal center