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Reaction of [η 5 :σ-Me 2 C(C 5 H 4 )(C 2 B 10 H 10 )]Ru(NH 2 Pr n ) 2 with Alkynes. Synthesis and Structural Characterization of Ruthenium Aminocarbene and Enamine Complexes

✍ Scribed by Sun, Yi; Chan, Hoi-Shan; Xie, Zuowei


Book ID
126892976
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
207 KB
Volume
25
Category
Article
ISSN
0276-7333

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Ruthenium-Mediated Coupling/Cycloadditio
✍ Yi Sun; Hoi-Shan Chan; Haitao Zhao; Zhenyang Lin; Zuowei Xie 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB 👁 1 views

Cyclopentadienyl and its derivatives (Cp ligands) are among the most extensively utilized p ligands in organometallic chemistry. In most organometallic reactions of transitionmetal complexes, the h 5 -Cp ligand plays the role of a spectator that stays tightly bound in h 5 fashion to the metal center