𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Ruthenium-Mediated Coupling/Cycloaddition of the Cyclopentadienyl Ligand in [{η5:σ-Me2C(C5H4)(C2B10H10)}Ru(NCCH3)2] with Alkynes

✍ Scribed by Yi Sun; Hoi-Shan Chan; Haitao Zhao; Zhenyang Lin; Zuowei Xie

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
157 KB
Volume
118
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Ruthenium-Mediated Coupling/Cycloadditio
Ruthenium-Mediated Coupling/Cycloaddition of the Cyclopentadienyl Ligand in [{η5:σ-Me2C(C5H4)(C2B10H10)}Ru(NCCH3)2] with Alkynes
✍ Yi Sun; Hoi-Shan Chan; Haitao Zhao; Zhenyang Lin; Zuowei Xie 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB

Cyclopentadienyl and its derivatives (Cp ligands) are among the most extensively utilized p ligands in organometallic chemistry. In most organometallic reactions of transitionmetal complexes, the h 5 -Cp ligand plays the role of a spectator that stays tightly bound in h 5 fashion to the metal center

Complexes of the (Tetramethylcyclobutadi
Complexes of the (Tetramethylcyclobutadiene)cobalt Fragment with Boratabenzene Ligands and an Unprecedented Formation of a Borabenzene Complex − Structures of (C4Me4)Co(3,5-Me2C5H3BSnMe3) with an Sn−B Bond and of the Dinuclear Complex [(C4Me4)Co(3,5-Me2C5H3B)]2O
✍ Gerhard E. Herberich; Tushar S. Basu Baul; Ulli Englert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th

Organometallic Compounds of the Lanthani
Organometallic Compounds of the Lanthanides. 127 [1] Synthesis of Monomeric Bis(cyclopentadienyl)lanthanide Tetrahydroborates with Bulky Cyclopentadienyl Ligands. Single Crystal X-ray Structures of [(η5-C5Me5)2SmBH4(THF)] and [(η5-C5Me4Et)2Y(μ-H)2BH2(THF)]
✍ Herbert Schumann; Markus R. Keitsch; Jörg Demtschuk; Stefan Mühle 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 171 KB 👁 2 views

The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4