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Reaction of α,β-Unsaturated Fischer Carbene Complexes with Allyl Alkoxide.

✍ Scribed by Ken Kamikawa; Atsushi Tachibana; Yasunori Shimizu; Kazuya Uchida; Masaru Furusyo; Motokazu Uemura


Publisher
John Wiley and Sons
Year
2006
Weight
31 KB
Volume
37
Category
Article
ISSN
0931-7597

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α,β-Unsaturated Fischer Carbene Complexe
✍ José Barluenga; Félix Fernández-Marí; Rosario González; Enrique Aguilar; Gustavo 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 428 KB 👁 1 views

The reaction of tert-butylalkynyl chromium Fischer carbene complex 1 with nitrones 2 affords β-enamino-ketoaldehydes 4 by the light-promoted rearrangement of the corresponding [3+2] cycloadduct carbene complexes 3. On the other hand,