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[4+1]/[2+1] Cycloaddition Reactions of Fischer Carbene Complexes with α,β-Unsaturated Ketones and Aldehydes

✍ Scribed by José Barluenga; Hugo Fanlo; Salomé López; Josefa Flórez


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
139 KB
Volume
119
Category
Article
ISSN
0044-8249

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α,β-Unsaturated Fischer Carbene Complexe
✍ José Barluenga; Félix Fernández-Marí; Rosario González; Enrique Aguilar; Gustavo 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 428 KB

The reaction of tert-butylalkynyl chromium Fischer carbene complex 1 with nitrones 2 affords β-enamino-ketoaldehydes 4 by the light-promoted rearrangement of the corresponding [3+2] cycloadduct carbene complexes 3. On the other hand,