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ChemInform Abstract: α,β-Unsaturated Fischer Carbene Complexes vs. 1,3-Dipoles: Reactions with Nitrones and Nitrilimines.

✍ Scribed by Jose Barluenga; Felix Fernandez-Mari; Rosario Gonzalez; Enrique Aguilar; Gustavo A. Revelli; Argimiro L. Viado; Francisco J. Fananas; Bernardo Olano

Publisher
John Wiley and Sons
Year
2001
Weight
39 KB
Volume
32
Category
Article
ISSN
0931-7597

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α,β-Unsaturated Fischer Carbene Complexe
α,β-Unsaturated Fischer Carbene Complexes vs. 1,3-Dipoles: Reactions with Nitrones and Nitrilimines
✍ José Barluenga; Félix Fernández-Marí; Rosario González; Enrique Aguilar; Gustavo 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 428 KB 👁 1 views

The reaction of tert-butylalkynyl chromium Fischer carbene complex 1 with nitrones 2 affords β-enamino-ketoaldehydes 4 by the light-promoted rearrangement of the corresponding [3+2] cycloadduct carbene complexes 3. On the other hand,