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ChemInform Abstract: Reactions of Stabilized Sulfur Ylides with α,β-Unsaturated Alkoxychromiumcarbene Complexes.

✍ Scribed by B. ALCAIDE; L. CASARRUBIOS; G. DOMINGUEZ; A. RETAMOSA; M. A. SIERRA

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199707088

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The active ketenylidene-(2a) or thioketenylidenetriphenylphosphoranes (2b) react with 2-benzylidene-1,3-indandione (1), 5-benzylidenebarbituric acid (11), and 4-benzylidene-1,2-diphenyl-3,5-pyrazolidinedione (16) to give the corresponding pyranones and thioxopyranones (3a,b, 12a,b) and (17a,b), resp