Reaction of ɛ-caprolactam with 1,1,3-trihydroperfluoropropanol catalyzed by phosphorous amide copper complexes
✍ Scribed by A. I. Rakhimov; N. A. Storozhakova; S. A. Kosenkova; E. A. Pugacheva
- Book ID
- 111459310
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 105 KB
- Volume
- 77
- Category
- Article
- ISSN
- 1070-3632
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📜 SIMILAR VOLUMES
## Abstract Using the __C__~2~‐symmetric bis‐oxazoline copper(II) catalyst **6f** as a chiral Lewis acid, α′‐phosphoric enones **2** undergo 1,3‐dipolar cycloaddition with nitrones **3** to provide isoxazolidines **4** with very high enantioselectivity and __endo/exo__ selectivity.
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