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Reaction of 3-sulfolene with 1,3-dienes, catalyzed by palladium complexes

โœ Scribed by R. V. Kunakova; F. V. Sharipova; G. A. Tolstikov; L. M. Zelenova; A. A. Panasenko; L. V. Spirikhin; U. M. Dzhemilev


Book ID
112443422
Publisher
Springer
Year
1980
Tongue
English
Weight
433 KB
Volume
29
Category
Article
ISSN
1573-9171

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Palladium(0) catalyzed reaction of 1,3-d
โœ M. Suzuki; Y. Oda; R. Noyori ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 246 KB

Reaction of 1,3-diene 1,4-epiperoxides with Pd(PPh314 catalyst forms the corresponding 4-hydroxy enones, syn diepoxides, and 1,4-dials as the major products. The results are interpreted as being due to competing Pd(O)/Pd(II) and Pd(O)/Pd(I) exchange