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Palladium-catalyzed reactions of 1,3-dienes with active methylene compounds. II.

โœ Scribed by Hata, Go.; Takahashi, Kuniyuki; Miyake, Akihisa

Book ID
120663829
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
916 KB
Volume
36
Category
Article
ISSN
0022-3263

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โœ M. Suzuki; Y. Oda; R. Noyori ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 246 KB

Reaction of 1,3-diene 1,4-epiperoxides with Pd(PPh314 catalyst forms the corresponding 4-hydroxy enones, syn diepoxides, and 1,4-dials as the major products. The results are interpreted as being due to competing Pd(O)/Pd(II) and Pd(O)/Pd(I) exchange