Reaction of Tertiary Cyclopropyl Silyl Ethers with Diethylaminosulfur Trifluoride: The Effects of Substituents on the Cleavage of the Cyclopropane Ring.
β Scribed by Masayuki Kirihara; Hiroko Kakuda; Makoto Tsunooka; Akihiro Shimajiri; Tomofumi Takuwa; Akihiko Hatano
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 148 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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The diastereocomplementarity of halo- and alkylcarbenes (paths a and b, respectively) was shown in the cyclopropanation reaction of 1. The conversion of 1 into 7,7-dimethylbicyclo[4.1.0]heptan-1,2-diols (Β±)-2 and (Β±)-3 represents an important transformation in a synthetic strategy towards phorbol de