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Reaction of tellurium tetrachloride with propargyl chloride

✍ Scribed by Potapov, V. A.; Khabibulina, A. G.; Musalova, M. V.; Chernyshev, K. A.; Amosova, S. V.

Book ID
121552899
Publisher
SP MAIK Nauka/Interperiodica
Year
2014
Tongue
English
Weight
171 KB
Volume
50
Category
Article
ISSN
1070-4280

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The reactions of 13 aliphatic ketones with tellurium tetrachloride has been studied with proton, carbon-13, and tellurium-I 25 NMR. Tellurium tetrachloride adds electrophilically to the a-carbon of the enol to form ketonyl tellurium trichlorides. Unsymmetric ketones gave mixtures of isomeric ketonyl