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Reaction of tellurium tetrachloride with acetylene

✍ Scribed by V. A. Potapov; M. V. Musalov; M. V. Musalova; S. V. Amosova

Book ID
106521433
Publisher
Springer
Year
2009
Tongue
English
Weight
178 KB
Volume
58
Category
Article
ISSN
1573-9171

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The reactions of 13 aliphatic ketones with tellurium tetrachloride has been studied with proton, carbon-13, and tellurium-I 25 NMR. Tellurium tetrachloride adds electrophilically to the a-carbon of the enol to form ketonyl tellurium trichlorides. Unsymmetric ketones gave mixtures of isomeric ketonyl