𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The reactions of tellurium tetrachloride with aliphatic monoketones

✍ Scribed by Daniel H. O'Brien; Kurt J. Irgolic; Chang-Kai Huang

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
666 KB
Volume
1
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

The reactions of 13 aliphatic ketones with tellurium tetrachloride has been studied with proton, carbon-13, and tellurium-I 25 NMR. Tellurium tetrachloride adds electrophilically to the a-carbon of the enol to form ketonyl tellurium trichlorides. Unsymmetric ketones gave mixtures of isomeric ketonyl tellurium trichlorides. Steric hindrance determines which ketonyl tellurium trichlorides form-Except for the ketonyl tellurium trichloride from 2-butanone, tellurium reacts preferentially with the least substituted a-carbon. Six methyl alkyl ketones also yielded appreciable amounts of diketonyl tellurium dichlorides. In all diketonyl tellurium dichlorides, tellurium is bonded to less hindered methylene carbons.

πŸ“œ SIMILAR VOLUMES

The reactions of tellurium tetrachloride
The reactions of tellurium tetrachloride with acetone
✍ Chang-Kai Huang; Harold Marhold; Daniel H. O'Brien; Kurt J. Irgolic πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 432 KB

## Abstract The reactions of acetone with tellurium tetrachloride have been studied with the aid of proton, carbon‐13, and tellurium‐125 NMR spectroscopy. In the absence of a proton scavenger, such as sodium hydrogen carbonate, at ambient temperature, a 2 : 1 ratio of acetone to tellurium tetrachlo

Rapid reactions of phthalocyanines with
Rapid reactions of phthalocyanines with tellurium tetrachloride in non-aqueous solutions
✍ Yutaka Kagaya; Hiroaki Isago πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 86 KB πŸ‘ 2 views

Rapid reactions of tetra(tert-butyl)phthalocyanine, H ~2~( tbpc ), and its zinc complex, [ Zn ( tbpc )], with tellurium tetrachloride ( TeCl ~4~) in non-aqueous solutions have been investigated. Upon mixing respective solutions containing the reactants, drastic spectral changes occurred in chlorofor

The reaction of cyclopentyl radicals wit
The reaction of cyclopentyl radicals with carbon tetrachloride
✍ Ian Matheson; John Tedder; Howard Sidebottom πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 448 KB

## Abstract The photolysis of azocyclopentane in the presence of cyclopentane–carbon tetrachloride mixtures has been investigated in the gas phase. Product analysis data have been used to determine the Arrhenius parameters for the reactions The rate data for chlorine atom abstraction from CCl~4~

The reaction of cyclohexyl radicals with
The reaction of cyclohexyl radicals with carbon tetrachloride
✍ Jim Currie; Howard Sidebottom; John Tedder πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 523 KB

## Abstract The photolysis of azocyclohexane, carbon tetrachloride, and cyclohexane at 360 nm has been investigated over a wide temperature range. At moderate temperatures a chain reaction ensues from which the following approximate rate constants could be determined assuming 2CCl~3~. β†’ C~2~Cl~6~,