O ( l D ) , produced from the photolysis ofN,O at 2139 A, reacts with N,O in accord with: We have used the method of chemical difference to obtain an accurate measure of k,/k, = 0.59 f 0.01. Furthermore, the quantum yield of production of O ( , P ) , either on direct photolysis or on deactivation o
Reaction of S(31D2) with N2O
β Scribed by R.J. Donovan; W.H. Breckenridge
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 674 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
Product (NzD? angular and velocity distributions were experimentally determined over a relative energy range of 1-16 eV. At the lowest energy. the reaction was conclusively shown to proceed by an impukive mode (stripping).
The rate of reaction of O(lD2) with X20 relative to that of reaction with neopentane has been determined by a competitive method. The value obtained, kI.&&op\_ = 0.38, is in good agreement with that determined previously\_ in this laboratory. by a different experimental technique. It is aiso fomd th
The reaction of CF3 radicals with Ha0 (D20) has been studied over the range of 533-723 K using the photolysis and the pyrolysis of CFJ as the free radical source. Arrhenius pa- rameters for the reactions where X = H or D, relative to CF:j radical recombination are given by log kHlkf'2 = (5.12 f 0.1