3-,4-Pyridyl and 4-quinolyl Grignard reagents were generated by the reaction of the corresponding phenyl sulfoxides with PhMgBr and give the adducts upon treatment with various aldehydes and ketones. The stereochemistry for the reaction
โฆ LIBER โฆ
Reaction of S-(2-pyridyl) thioates with Grignard reagents. Convenient method for the preparation of ketones
โ Scribed by Mukaiyama, Teruaki.; Araki, Masashi.; Takei, Hisashi.
- Book ID
- 120240222
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 382 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Reactions of pyridyl and quinolyl sulfox
โ
Naomichi Furukawa; Tadao Shibutani; Kazunori Matsumura; Hisashi Fujihara; Shiger
๐
Article
๐
1986
๐
Elsevier Science
๐
French
โ 241 KB
Ligand exchange reactions of aryl pyridy
โ
Tadao Shibutani; Hisashi Fujihara; Naomichi Furukawa; Shigeru Oae
๐
Article
๐
1991
๐
John Wiley and Sons
๐
English
โ 916 KB
Convenient ketone synthesis by the react
โ
Kim, Sunggak; Lee, Jae In
๐
Article
๐
1983
๐
American Chemical Society
๐
English
โ 440 KB
Cp2TiCl2-Catalyzed Grignard exchange rea
โ
Fumie Sato; Hiroaki Ishikawa; Masao Sato
๐
Article
๐
1981
๐
Elsevier Science
๐
French
โ 229 KB
Copper ion promoted esterification of (S
โ
Kim, Sunggak; Lee, Jae In
๐
Article
๐
1984
๐
American Chemical Society
๐
English
โ 630 KB
A convenient preparation of bipyridines
โ
Tsutomu Kawai; Naomichi Furukawa; Shigeru Oae
๐
Article
๐
1984
๐
Elsevier Science
๐
French
โ 244 KB
Substituted 2-methylsulfinyl pyridines react with Grignard reagents to afford 6,6'-disubstituted-2,2 '-bipyridines (substituents: MeS, Cl, Br, H) in fair yields. Recently, we have shown that the reaction of benzyl 2-pyridyl sulfoxide with Grignard reagents or organolithium reagents gives intramolecu