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Reaction of Perfluoroalkanesulfinyl Chlorides with Enamines: A Facile Synthesis of α-Perfluoroalkanesulfinyl Ketones and Aldehydes

✍ Scribed by Xiaobo LI; Lingjun CHEN; Xiaojin WANG; Jintao LIU

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
163 KB
Volume
27
Category
Article
ISSN
0256-7660

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The reactiom of enamina (la-b, 4, 6 ) with fluorinated acyl chlorida (2.4) produced fluorinated 1,3-diketona (3a-O and 1,3-keto-aldehyda (7a-c) in good yieldr M well M byproductr fluorinated acykmida ((k-c). It ir pro& that the resctionm involve nuckophilic attack by the Catom and/or N-atom of the e