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Reactions of enamines with fluorinated acyl chlorides — Synthesis of fluorinated 1,3-diketones and 1,3-keto-aldehydes

✍ Scribed by He Hai-Ying; Qu Yan-Ling; Zhao Cheng-Xue

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
485 KB
Volume
16
Category
Article
ISSN
0256-7660

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✦ Synopsis

The reactiom of enamina (la-b, 4, 6 ) with fluorinated acyl chlorida (2.4) produced fluorinated 1,3-diketona (3a-O and 1,3-keto-aldehyda (7a-c) in good yieldr M well M byproductr fluorinated acykmida ((k-c). It ir pro& that the resctionm involve nuckophilic attack by the Catom and/or N-atom of the enamina on scyl carbon of the fluorinated acyl chlorida.

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