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Niobium(V) chloride-catalyzed synthesis of α-aminonitriles with simultaneous reaction of aldehydes, amines and trimethylsilyl cyanide

✍ Scribed by Anjoy Majhi; Sung Soo Kim; Ho Sub Kim

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
152 KB
Volume
22
Category
Article
ISSN
0268-2605

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Solvent-free synthesis of α-aminonitrile
Solvent-free synthesis of α-aminonitriles from aldehydes, amines and trimethylsilyl cyanide catalyzed by thallium(III) chloride tetrahydrate
✍ Anjoy Majhi; Sung Soo Kim; Santosh T. Kadam 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 163 KB

## Abstract A straightforward and efficient method has been developed for the synthesis of α‐aminonitriles by combining aldehydes, amines and trimethylsilyl cyanide in the presence of a catalytic amount of thallium(III) chloride tetrahydrate (1 mol%) under solvent‐free conditions at room temperatur