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Reaction of H2O with H produced by the 266 nm photolysis of HI

✍ Scribed by K. Honda; M. Takayanagi; T. Nishiya; H. Ohoyama; I. Hanazaki

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 451 KB
Volume: 180
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)90327-6

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✦ Synopsis

The elementary reachon, H+H,O+OH+H*, has been studied in the flowing mixture of HI and HZ0 irradiated at 266 nm. The nascent rotational distributions of OH are of Boltzmann-type with a remarkably non-statistical partition over the n-doublet sublevels, while the spin-orbit components are populated statistically. Weak dependence on the collision energy is suggested. These results are shown to be explained with a classical model based on the direct stripping mechanism with the reaction barrier at a later stage of the reaction coordinate.

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