## Abstract Fourier‐transform ion cyclotron resonance mass spectrometry has been used to examine gas‐phase reactions of four different nitroxide free radicals with eight positively charged pyridyl and phenyl radicals (some containing a Cl, F, or CF~3~ substituent). All the radicals reacted rapidly
✦ LIBER ✦
Reaction of gas-phase radicals from combustion with radical scavengers
✍ Scribed by Kouji Furusawa; Toshiyuki Kawamura; Yoshiaki Akutsu; Mitsuru Arai; Masamitsu Tamura
- Book ID
- 114379382
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 403 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1352-2310
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## The reaction (3) i-CpF, + CCli-C3F&l + CCl3 was investigated in the gas phase over the range 80-225°C using the photolysis of heptafluoroisopropyl iodide as the source of radicals. The rate constant, based on the value of 1013 36 cm3 mol log(k3/cm3 mol-' s-l) = (13.10 2 0.20) -(14000 \* 280)/0
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