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Radical scavenging reactions of α-tocopherol II. The reaction with some alkyl radicals

✍ Scribed by Shiro Urano; Shinju Yamanoi; Yuji Hattori; Mitsuyoshi Matsuo


Book ID
112771493
Publisher
Springer-Verlag
Year
1977
Tongue
English
Weight
184 KB
Volume
12
Category
Article
ISSN
0024-4201

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Reactions of BrCl with alkyl radicals.
✍ P.S Skell; H.N Baxter III; J.M Tanko 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 212 KB

It is demonstrated that photohalogenations of low reactivity substrates with BrCl occurs mainly with Cl' selectivity. With tertiary or benzylic hydrogens in the substrate, mainly Br' selectivity is observed. These observations are rationalized, taking into account the relative concentrations of ha