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REACTION OF EARLY TRANSITION METAL COMPLEXES WITH MACROCYCLES. IV. SYNTHESIS AND STRUCTURE OF [(PPh 4 )] 2 [18-CROWN-6·(VCl 4 ) 2 ] AND 18-CROWN-6·VCl 3 ·H 2 O

✍ Scribed by Kynast, Ulrich; Bott, Simon G.; Atwood, Jerry L.

Book ID
120042232
Publisher
Taylor and Francis Group
Year
1988
Tongue
English
Weight
450 KB
Volume
17
Category
Article
ISSN
0095-8972

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✍ T. Stanley Cameron; Andreas Decken; Evgeny G. Ilyin; Grigori B. Nikiforov; Jack 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 1 views

## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__