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Complexes of 18-crown-6 with oxonium ions derived from transition metal chlorides and hydrochloric acid: 18-crown-6.H 3 O + . FeCl 4− , 18-crown-6.H 3 O + .InCl 4− , (18-crown-6.H 3 O + ) 2 .Pd 2 Cl 62−

✍ Scribed by Chênevert, Robert; Chamberland, Daniel; Simard, Michel; Brisse, François


Book ID
127348948
Publisher
NRC Research Press
Year
1989
Tongue
French
Weight
330 KB
Volume
67
Category
Article
ISSN
0008-4042

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18-Crown-6 and Titanium Tetrafluoride −
✍ T. Stanley Cameron; Andreas Decken; Evgeny G. Ilyin; Grigori B. Nikiforov; Jack 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 1 views

## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__