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Reaction of Dimethyl Sulfoxide with Grignard Reagents

✍ Scribed by Oda, Ryohei; Yamamoto, Keiji

Book ID
121304941
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
329 KB
Volume
26
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Reactions of pyridyl and quinolyl sulfox
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3-,4-Pyridyl and 4-quinolyl Grignard reagents were generated by the reaction of the corresponding phenyl sulfoxides with PhMgBr and give the adducts upon treatment with various aldehydes and ketones. The stereochemistry for the reaction

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Pyridyl Grignard reagents were prepared from the corresponding iodopyridine and EtMgBr. New cross coupling reactions of the Grignard reagents with azaheterocycles took place on the sulfinyl sulfur atom to afford biazaheteroaryls.