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Reaction of dicarbomethoxycarbene with quadricyclane

✍ Scribed by Merry L. Tetef; Maitland Jones Jr.

Book ID
104229920
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
167 KB
Volume
25
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

The Reaction of Dihalocarbenes with Quad
The Reaction of Dihalocarbenes with Quadricyclane
✍ Charles William Jefford; Jacques Roussilhe; Mihail Papadopoulos πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 German βš– 797 KB

The action of dichlorocarbene, generated in excess by phase-transfer catalysis at 20", on quadricyclane 2 resulted in a 7% conversion to at least seven products. The major component (51 % relative yield) was 3,4-exo-dichlorobicyclo[3.2.1 ]octa-2,6-diene (12). Cl c 1 c1 c1 16 12