The Reaction of Dihalocarbenes with Quad
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Charles William Jefford; Jacques Roussilhe; Mihail Papadopoulos
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Article
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1985
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John Wiley and Sons
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German
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The action of dichlorocarbene, generated in excess by phase-transfer catalysis at 20", on quadricyclane 2 resulted in a 7% conversion to at least seven products. The major component (51 % relative yield) was 3,4-exo-dichlorobicyclo[3.2.1 ]octa-2,6-diene (12). Cl c 1 c1 c1 16 12