The Reaction of Dihalocarbenes with Quadricyclane

✍ Scribed by Charles William Jefford; Jacques Roussilhe; Mihail Papadopoulos

• Publisher: John Wiley and Sons
• Year: 1985
• Tongue: German
• Weight: 797 KB
• Volume: 68
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19850680607

✦ Synopsis

The action of dichlorocarbene, generated in excess by phase-transfer catalysis at 20", on quadricyclane 2 resulted in a 7% conversion to at least seven products. The major component (51 % relative yield) was 3,4-exo-dichlorobicyclo[3.2.1 ]octa-2,6-diene (12). Cl c 1 c1 c1 16 12