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Reaction of cyclocarbonates with amines as an alternative route to polyurethanes: A quantum-chemical study of reaction mechanism

✍ Scribed by Zabalov, M. V.; Tiger, R. P.; Berlin, A. A.

Book ID
110160381
Publisher
Springer
Year
2011
Tongue
English
Weight
172 KB
Volume
441
Category
Article
ISSN
0012-5008

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Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce