Mechanism of Reactions of Thiols and Disulfides with Dihaloalkanes: A Quantum-Chemical Study
โ Scribed by V. A. Shagun; E. N. Deryagina; N. A. Korchevin; N. V. Russavskaya
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 107 KB
- Volume
- 75
- Category
- Article
- ISSN
- 1070-3632
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๐ SIMILAR VOLUMES
## Abstract Cysteine sulfenyl thiocyanate (CSSCN) reacts with thiols at pH 0 to cleanly yield disulfides. 2โMercaptoethanol (2โMESH), 3โmercaptopropionic acid (3โMPASH), penicillamine (PENSH), and glutathione (GSH) react with CSSCN to give the corresponding mixed disulfides: 2โMESSC, 3โMPASSC, PENS
## Abstract The reaction mechanism of OBrO with OH has been studied using the B3LYP/6โ311+G(d,p) and the highโlevel electronโcorrelation CCSD(T)/6โ311+G(d,p) at singleโpoint. The results show that the title reaction could probably proceed by four possible schemes, generating HOBr+O~2~, HBr+O~3~, Br