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The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: a new route to secondary amines

✍ Scribed by Fabio Doctorovich; Cecilia Trápani

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 302 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00810-2

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✦ Synopsis

Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce dibenzylamine and piperidine, respectively.

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