𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reaction of cycloalkanone enamines with allylic compounds in the presence of palladium complexes

✍ Scribed by Hiroshi Onoue; Ichiro Moritani; Shun-Ichi Murahashi

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
198 KB
Volume
14
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of alkyl perfluoroalkyl ketone
Synthesis of alkyl perfluoroalkyl ketones reactions of allyl perfluoroalkanoates with acyl chlorides in the presence of palladium(0)
✍ Qing-Yun Chen; Jian-Guo Chen 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 674 KB

The reactions of fluorocarbanions derived from palladium(O) mediated decomposition of ally1 esters of fluoroalkylether acids, RfC02CH2CH=CH2(Rf=C3F70[CF(CF3)CF20]nCF(CF3), n=O,l), with acyl chlorides yielded en01 esters of hemifluorinated ketones, RR'C=C(Rf)OCOCHRR', n=O, 4; n=l, 5, plus a very smal

Mechanisms in the Reaction of Palladium(
Mechanisms in the Reaction of Palladium(II)–π-Allyl Complexes with Aryl Halides: Evidence for NHC Exchange Between Two Palladium Complexes
✍ Adrien T. Normand; Mikhail S. Nechaev; Kingsley J. Cavell 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 505 KB

## Abstract A detailed experimental and DFT study (PBE level) of the reaction of [Pd(η^3^‐C~3~H~5~)(tmiy)(PR~3~)]BF~4~ (tmiy=tetramethylimidazolin‐2‐ylidene, PR~3~=phosphane), precursors to monoligated Pd^0^ species, with aryl electrophiles yielding 2‐arylimidazolium salt is reported. Experiments e