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Formation of 1,3-dienetricarbonyliron complexes from the reaction of dipotassium tetracarbonylferrate with allylic compounds

✍ Scribed by Yasuo Butsugan; Akihiko Yamashita; Shuki Araki


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
398 KB
Volume
287
Category
Article
ISSN
0022-328X

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Nitration of ally1 esters with N02BF4 proceeds with nucleophilic participation of carbonyl and yields nitro-substituted oxonium salts. Nitration of alkenes with N02BF4 1 may yield nitroalkenes 'a, 1,2-fluoronitroderivatives lb or solvoadducts I'. Here we report results showing that the interaction