Reactions of π-allylic complexes of palladium with methyl formate
✍ Scribed by Wilhelm Keim; Johannes Becker; Peter Kraneburg; Ralf Greven
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 447 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0304-5102
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📜 SIMILAR VOLUMES
n-Allylic acetylacetonatopalladium complexes were found to react in the atmosphere of carbon monoxide to give allylic acetylacetones(1). This type of ligand coupling reactions could be applied generally for some allylic palladium complexes, in which a ligand other than halogen was included, that is
## Abstract A detailed experimental and DFT study (PBE level) of the reaction of [Pd(η^3^‐C~3~H~5~)(tmiy)(PR~3~)]BF~4~ (tmiy=tetramethylimidazolin‐2‐ylidene, PR~3~=phosphane), precursors to monoligated Pd^0^ species, with aryl electrophiles yielding 2‐arylimidazolium salt is reported. Experiments e