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Reaction of C(PPh3)2 with MI2 Compounds (M = Zn, Cd) – Formation and Crystal Structures of [I2Zn{C(PPh3)2}], [(I2Cd{C(PPh3)2})2] and the Salt-Like Compounds (HC{PPh3}2)[MI3(THF)] and (HC{PPh3}2)2[ZnI4]

✍ Scribed by Wolfgang Petz; Bernhard Neumüller

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
517 KB
Volume
2011
Category
Article
ISSN
1434-1948

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📜 SIMILAR VOLUMES

Carbodiphosphorane C(PPh3)2 as a Single
Carbodiphosphorane C(PPh3)2 as a Single and Twofold Lewis Base with Boranes: Synthesis, Crystal Structures and Theoretical Studies on [H3B{C(PPh3)2}] and [{(μ-H)H4B2}{C(PPh3)2}]+
✍ Wolfgang Petz; Florian Öxler; Bernhard Neumüller; Ralf Tonner; Gernot Frenking 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB 👁 2 views

## Abstract The donor‐acceptor complex [(H~3~B){C(PPh~3~)~2~}] (2) has been synthesized by treating B~2~H~6~ with C(PPh~3~)~2~ and its geometry determined by X‐ray structure analysis. Treatment of 2 with DME yields the complex [{(μ‐H)H~4~B~2~}{C(PPh~3~)~2~}][B~2~H~7~] (4), which has also been isola