✦ LIBER ✦

Reaction of chlorine with bromine

✍ Scribed by J. Olbregts

Publisher: John Wiley and Sons
Year: 1974
Tongue: English
Weight: 316 KB
Volume: 6
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550060309

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✦ Synopsis

Abstract

Different possible mechanisms for the gas phase reaction of formation of bromine chloride from bromine and chlorine are discussed. The rate of the reaction has been deduced from photometric measurements in conventional static reactors of surface‐to‐volume ratio ranging between 0.6 and 3 cm^−1^, at temperatures between 51 and 113°C. Experimental data show that (1) the observed reaction is predominantly heterogeneous, and (2) the homogeneous reaction must proceed by an atomic chain mechanism initiated by Br atoms.

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