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Chlorination and Bromination of Dialkyl Tellurides

✍ Scribed by Thomas M. Klapötke; Burkhard Krumm; Peter Mayer; Holger Piotrowski; Oliver P. Ruscitti

Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
122 KB
Volume
628
Category
Article
ISSN
0372-7874

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Catalytic Asymmetric Bromination and Chl
Catalytic Asymmetric Bromination and Chlorination of β-Ketoesters
✍ Mauro Marigo; Nagaswami Kumaragurubaran; Karl Anker Jørgensen 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB

## Abstract The first general catalytic asymmetric bromination and chlorination of β‐ketoesters has been developed. The reactions proceed for both acyclic and cyclic β‐ketoesters catalyzed by chiral bisoxazolinecopper(II) complexes giving the corresponding optically active α‐bromo‐ and α‐chloro‐β‐k