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Reaction of Carboxylic Acids and Isonitriles in Small Spaces

โœ Scribed by Hou, Jun-Li; Ajami, Dariush; Rebek, Julius

Book ID
124150530
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
622 KB
Volume
130
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Facile reaction of carboxylic acids with
Facile reaction of carboxylic acids with isonitriles in toluene
โœ Jason G. Polisar; Ling Li; Jack R. Norton ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 281 KB

Isonitriles react with low concentrations of carboxylic acids in toluene at 110 ยฐC to give N-formylamides in yields generally above 70%. These concentrations can be obtained either by syringe pump addition of a toluene solution of the acid, or by using a suspension of the acid if it has limited solu