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Reaction of Buckminsterfullerene with ortho-Quinodimethane: a New Access to Stable C60 Derivatives

✍ Scribed by Dipl.-Chem. Pavel Belik; Dipl.-Chem. Andreas Gügel; Jochen Spickermann; Prof. Dr. Klaus Müllen


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
385 KB
Volume
32
Category
Article
ISSN
0044-8249

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New reaction of pyridinium ylide with 2,
✍ Yuri G. Gololobov; Olesya A. Linchenko; Pavel V. Petrovskii; Victor N. Khrustale 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB 👁 1 views

## Abstract A new reaction of pyridinium ylide (**4**) with 2,4,6‐trinitrofluorobenzene leading to stable negatively charged heptatriene moiety (**6**) is described. This reaction proceeds via a new route of decomposition of intermediate σ‐complex (**5**) occurring with the formation of ethylfluoro