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A new approach to the synthesis of 2-substituted indoles: reaction of dimetallated ortho-trimethylsilylmethylanilides with esters

โœ Scribed by Giuseppe Bartoli; Gianni Palmieri; Marino Petrini

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
386 KB
Volume
46
Category
Article
ISSN
0040-4020

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โœ Giuseppe Bartoli; Gianni Palmieri; Marcella Bosco; Renato Dalpozzo ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 302 KB

The reaction of three moles of vinylmagnesium bromide wi.th one mole of nitroarene leads to the formation of indoles after aqueous work up of the mixture. Good yields are obtained with orthosubstituted nitroarenes.