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Reaction of bis(trimethylsilyl) sulfate with peroxides and oxides

โœ Scribed by M. G. Voronkov; E. A. Maletina; V. K. Roman


Book ID
112441932
Publisher
Springer
Year
1978
Tongue
English
Weight
228 KB
Volume
27
Category
Article
ISSN
1573-9171

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Oxidation of tetraphosphacubane by bis(t
โœ Xiao-Bo Ma; Manfred Birkel; Thomas Wettling; Manfred Regitz ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 574 KB

Although the nucleophilicity/basicity at the phosphorus atom of the tetraphosphacubane 2 is reduced, apparently owing to the participation of the lone pairs of electrons in the PIC u bonds, stepwise oxidation of the phosphoms atoms with bis(trimethylsily1) peroxide or sulfur (in the presence of trie