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Reaction of bis(trimethylsilyl) sulfate with phosphorus acid chlorides

โœ Scribed by A. N. Pudovik; G. V. Romanov; T. Ya. Stepanova


Book ID
112443780
Publisher
Springer
Year
1979
Tongue
English
Weight
165 KB
Volume
28
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES


The reaction of tris(trimethylsilyl)sila
โœ M. Ballestri; C. Chatgilialoglu; N. Cardi; A. Sommazzi ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 268 KB

Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb