Nef Reaction of Benzylic and Secondary Nitro Compounds Using Bis(Trimethylsilyl)Peroxide 1
β Scribed by Shahi, Shatrughan P.; Vankar, Vashwant D.
- Book ID
- 120466756
- Publisher
- Taylor and Francis Group
- Year
- 1999
- Tongue
- English
- Weight
- 166 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0039-7911
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Lithium reduction of (Z)-l,2-bis(trimethylsilyl)-l-phenylethene (l) yields the dianion of the (E)-isomer (3) and via Schlenk dimerization dilithium 1.4-diyl-l,4-diphenyl-l,2,3,4-tetrakis(trimethylsilyl)butane (4). The NMR parameters for both systems are reported and their solution structures are dis
## Abstract 5β(2βAminophenyl)β6βazauracil 1 was converted to 7β(6βazauracilβ5βyl)isatin 3, semicarbazone 4 of which was recyclized to 2,6βbis(6βazauracilβ5βyl)aniline 5. This one served as a starting compound for preparation of other noncondensed two nuclear heterocycles 7, 9, 10 and condensed 1,2,