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Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand

✍ Scribed by Christopher S. Griffith; George A. Koutsantonis; Brian W. Skelton; Allan H. White

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 551 KB
Volume: 117
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200500224

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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,