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Reaction of 6,6-dibromobicyclo[3.1.0]hexane with methyllithium. Efficient trapping of 1,2-cyclohexadiene by styrene

โœ Scribed by Moore, William Robert.; Moser, William R.


Book ID
126889821
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
722 KB
Volume
35
Category
Article
ISSN
0022-3263

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6-bromo-6-(trimethylstannyl)bicyclo[3.1.
โœ Andreas Runge; Wolfram Sander ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

Flash vacuum pyrolysis and matrix-isolation studies of 6bromo-6-(trimethylstannyl)bicyclo[3.l.Olhexane (1) gave evidence for the formation of 1,2-c.yclohexadiene (2) from this precursor. At high temperatures (>6OO'C) 2 is not stable and fragmentates to I-butene-3yne (4) and ethylene.