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Reaction of 9,9-dibromobicyclo[6.1.0]non-2-ene-with methyllithium

โœ Scribed by Cardenas, Carlos G.; Shoulders, Ben A.; Gardner, Pete D.


Book ID
126296998
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
447 KB
Volume
32
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


1,2-cyclooctadiene, a product observed f
โœ E.T. Marquis; P.D. Gardner ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

It is well established that the reaction between ~-dibromocycIopropcmes and methyllithium generally affords allenes (1,2,3) and evidence has been presented which suggests that a carbene or carbenoid complex is on intermediate in the process (4,5,6). The reaction of strained methylenedibromocycloprop