✦ LIBER ✦

Reaction model of the dimer photoinitiation reaction in diacetylene crystals

✍ Scribed by H. Gross; W. Neumann; H. Sixi

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 548 KB
Volume: 95
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80360-1

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✦ Synopsis

lkc SI~0~t-ch3in dima. lrinicr. tr'lranler inter-ndi3rrs. c'lc'. of lfiis rstr3ordirm-y reaction have ban slrtbili/etl ai low ienlper;lIures and have been 31131~ /cd bg optical 1-81 311d ESR si>ectroscopy [5]. l'our ph~~roprodurr series have been identified [6] : 111c dir3dical DR,, srrics (with 1 <II < 6). the asym-I~ICITIC cxhr'n~ AC,, series (wirh 11 b 2). the dicarbene Ut;, scrirs (with II Z 7) and the stable otigomer SO,, series (wirb II 2 3). AI short chain length the DR,l iulerruediares are predominant -and are the only ones 10 be disc'usscd in this paper, since we are concerned 'olumc 95. number 6

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