The mechanism of the low temperature polymerization reaction in diacetylene crystals
โ Scribed by W. Neumann; H. Sixl
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 813 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
lkc SI~0~t-ch3in dima. lrinicr. tr'lranler inter-ndi3rrs. c'lc'. of lfiis rstr3ordirm-y reaction have ban slrtbili/etl ai low ienlper;lIures and have been 31131~ /cd bg optical 1-81 311d ESR si>ectroscopy [5]. l'our ph~~roprodurr series have been identified [6] : 111c dir3dical DR,, srrics (with 1 <
The tune dependence of the optical absorption dunng the photopolymenzatlon of TS single crystals has been mvestl-@ted in the spectral region oi the absorption of two dliferent photoproducts A and B. The obsemed hrnz constants range from 50 ns to mfiity and are temperature dependent 1~1th an actlvatl