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Reaction mechanisms of peroxyl and c-centered radicals with sulfhydryls

✍ Scribed by Simic, Michael G.; Hunter, Edward P.L.

Book ID
122780016
Publisher
Elsevier Science
Year
1986
Weight
304 KB
Volume
2
Category
Article
ISSN
0748-5514

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Alrstract--Trialkyl phosphites react with cyanoisopropylperoxyl radicals, generated by thermolysis of azobis(isobutyronitrile) in the presence of oxygen, to give the corresponding phosphates with rate constants of the order of 103 M -~ sec -~ at 65Β°C. Phenyl phosphites are oxidized also. A small amo